Copper-Catalyzed Highly Selective Hydrosilylation of Silyl or Boryl Alkene: A Method for Preparing Chiral Geminated Disilyl and Borylsilyl Reagents

作者：Min Zhang, Yuqi Ji, Zheng Zhang, Chun Zhang · 发表于：Organic Letters · 年份：2022 · DOI：10.1021/acs.orglett.2c00858 · 被引用次数：37 · 研究领域：Organoboron and organosilicon chemistry、Catalytic Cross-Coupling Reactions、Advanced Synthetic Organic Chemistry

The copper-catalyzed highly selective hydrosilylation of silyl or boryl alkene has been developed. This chemistry could afford a practical method for preparing chiral geminated disilyl and borylsilyl reagents, which are useful organosilanes and versatile synthons for organic synthesis. The experimental data suggested that this reaction could be compatible with a variety of functional groups. Furthermore, the utility of the gem-dimetal compounds, which could be prepared by this chemistry, has been well illustrated by further transformations.