Spectroscopic characterization of two boron heterocyclic radicals in the solid neon matrix

作者：Jiaping Xu, Xin Xu, Danyang Li, Jiwen Jian · 发表于：Physical Chemistry Chemical Physics · 年份：2022 · DOI：10.1039/d2cp00076h · 被引用次数：4 · 研究领域：Organoboron and organosilicon chemistry、Radical Photochemical Reactions、Luminescence and Fluorescent Materials

multiple hydrogen-atom transfer and rearrangement reactions. The observation of species A and further photo-isomerization to species B is consistent with theoretical predictions that these reactions are thermodynamically exothermic and kinetically facile. This is an exciting example of the synthesis of borole derivatives through multiple hydrogen-atom transfer and rearrangement reactions of borinine compounds induced by light irradiation. The present findings provide new insight into the future design and synthesis of the corresponding boron heterocyclic compounds.