“Three‐in‐One” Strategy that Ensures V 2 O 5 · n H 2 O with Superior Zn 2+ Storage by Simultaneous Protonated Polyaniline Intercalation and Encapsulation

作者：Jingjing Sun, Yunfeng Zhao, Yanyan Liu, Hanmei Jiang, Chi Huang, Miao Cui, Tao Hu, Changgong Meng, Yifu Zhang · 发表于：Small Structures · 年份：2022 · DOI：10.1002/sstr.202100212 · 被引用次数：65 · 研究领域：Advanced battery technologies research、Perovskite Materials and Applications、Supercapacitor Materials and Fabrication

The structural engineering of vanadium oxides is considered as a research hotspot for enhancing their electrochemical performances applied to aqueous zinc‐ion batteries (AZIBs). In regard to the laggard Zn 2+ transfer kinetic and fragile structure of V 2 O 5 · n H 2 O, herein, a feasible “three‐in‐one” strategy is adopted to design the structural engineering of V 2 O 5 · n H 2 O nanobelts through simultaneous protonated polyaniline intercalation and encapsulation (denoted as P‐VOH@P) to boost their Zn 2+ storage. First, the enlarged interlayer pillared by polyaniline accelerates Zn 2+ transfer speed and weakens electrostatic attraction between negative [VO] units and positive Zn 2+ . Second, polyaniline shell directly stabilizes the P‐VOH@P heterostructure. Third, the composition of protonated polyaniline not only improves the conductivity, but also contributes partial capacity though the reversible intrachain electronic migration. As expected, the Zn//P‐VOH@P cell exhibits specific capacities of 387 mAh g −1 with low‐mass‐loading cathode (2 mg cm −2 ) and 345 mAh g −1 with high‐mass‐loading cathode (5 mg cm −2 ) in coin cells and 360 mAh g −1 in pouch cells at 0.1 A g −1 . Furthermore, the Zn//P‐VOH@P cell shows low capacity decay and good rate property. Herein, light is shed on a new strategy of engineering the vanadium oxide structure for postgeneration cathode material and paves a novel way to the advanced energy‐storage system.