Synthetic Photoelectrochemistry

作者：Joshua P. Barham, Burkhard König · 发表于：Angewandte Chemie International Edition · 年份：2019 · DOI：10.1002/anie.201913767 · 被引用次数：454 · 研究领域：Advanced Photocatalysis Techniques、Advanced Chemical Sensor Technologies、Radical Photochemical Reactions

Photoredox catalysis (PRC) and synthetic organic electrochemistry (SOE) are often considered competing technologies in organic synthesis. Their fusion has been largely overlooked. We review state-of-the-art synthetic organic photoelectrochemistry, grouping examples into three categories: 1) electrochemically mediated photoredox catalysis (e-PRC), 2) decoupled photoelectrochemistry (dPEC), and 3) interfacial photoelectrochemistry (iPEC). Such synergies prove beneficial not only for synthetic "greenness" and chemical selectivity, but also in the accumulation of energy for accessing super-oxidizing or -reducing single electron transfer (SET) agents. Opportunities and challenges in this emerging and exciting field are discussed.