A V 2 O 3 @N–C cathode material for aqueous zinc‐ion batteries with boosted zinc‐ion storage performance

作者：Huaizheng Ren, Jian Zhang, Bo Wang, Hao Luo, Fan Jin, Zhang Tian-ren, An Ding, Bowen Cong, Dianlong Wang · 发表于：Rare Metals · 年份：2022 · DOI：10.1007/s12598-021-01892-0 · 被引用次数：84 · 研究领域：Advanced battery technologies research、Supercapacitor Materials and Fabrication、Advancements in Battery Materials

Abstract The discontinuity of new types of clean energy, such as wind power and solar cells, has promoted the development of large‐scale energy storage systems (EES). Rechargeable aqueous zinc‐ion batteries (ZIBs) have received extensive attention due to their inherent safety and low cost. At this stage, the performance of ZIBs is still limited by cathode materials. In this work, we have constructed a ZIBs cathode material‐V 2 O 3 @N–C, through surface coating and N atom doping. The N‐doped carbon coating endows V 2 O 3 @N–C with excellent structural stability and enhances its electrical conductivity. As a result, V 2 O 3 @N–C cathode delivers exceptional reversible of Zn 2+ intercalation/deintercalation. The fabricated Zn/V 2 O 3 @N–C batteries exhibit high capacity of 274.6 mAh·g −1 at 5 A·g −1 and excellent capacity retention of 94% after 2000 cycles. The reversible intercalation/deintercalation of Zn 2+ in the V 2 O 3 @N–C cathode is proved by ex‐situ testing methods. It is believed that this work should inject new vitality into the development of ZIBs cathode.