Synthesis of β-nitro ketones from geminal bromonitroalkanes and silyl enol ethers by visible light photoredox catalysis

作者：Haoying Cao, Shanshan Ma, Yanhong Feng, Yawen Guo, Peng Jiao · 发表于：Chemical Communications · 年份：2022 · DOI：10.1039/d1cc06529g · 被引用次数：31 · 研究领域：Radical Photochemical Reactions、Sulfur-Based Synthesis Techniques、Synthesis and Catalytic Reactions

Various β-nitro ketones, including those bearing a β-tertiary carbon, were prepared from geminal bromonitroalkanes and trimethylsilyl enol ethers of a broad range of ketones by visible light photoredox catalysis, which were then easily converted into β-amino ketones, 1,3-amino alcohols, α,β-unsaturated ketones, β-cyano ketones and γ-nitro ketones.