Lignin/Si Hybrid Carbon Nanofibers towards Highly Efficient Sustainable Li-ion Anode Materials

作者：Mario Alberto Gómez Culebras, Gearoid A. Collins, Anne Beaucamp, Hugh Geaney, Maurice N. Collins · 发表于：Engineered Science · 年份：2022 · DOI：10.30919/es8d608 · 被引用次数：80 · 研究领域：Advancements in Battery Materials、Supercapacitor Materials and Fabrication、Advanced Battery Materials and Technologies

As fossil fuel resources dwindle and new regulations for a cleaner and safer environment come onstream, there is a growing interest in developing new sustainable feedstocks for future applications.Lignocellulosic biomass is the feedstock of choice but remains underutilized and is mostly considered waste.Therefore, the present study shows the preparation of ligninderived carbon nanofibre (CNFs)/Si hybrid nanostructures to be used as high-performance anodes for Li-ion batteries.Scanning electron microscopy (SEM) shows the evolution of the morphology after each processing step (electrospinning, stabilization, and carbonization) and as a function of the Si content.The electrochemical analysis of the electrodes produced shows promising capacity values.The addition of Si elevated the achievable specific capacity of CNF, with 5, 10, and 15% of Si reaching respective capacity values of 274, 439, 602, and 921 mAh g -1 .Thus, these results show the enormous potential of lignocellulose waste materials as high-performance energy storage materials.