Electro-Reforming Polyethylene Terephthalate Plastic to Co-Produce Valued Chemicals and Green Hydrogen

作者：Jianying Wang, Xin Li, Ting Zhang, Yuetian Chen, Tianfu Wang, Yixin Zhao · 发表于：The Journal of Physical Chemistry Letters · 年份：2022 · DOI：10.1021/acs.jpclett.1c03658 · 被引用次数：202 · 研究领域：Electrocatalysts for Energy Conversion、CO2 Reduction Techniques and Catalysts、Advanced Photocatalysis Techniques

Upcycling plastic waste pollution for sustainable resources and energy is an ideal solution to plastic waste-related environmental issues. Polyethylene terephthalate (PET), one of the most prominent single-use daily plastics with up to millions of tons produced annually, has recently been explored with respect to chemical recycling to ameliorate its environmental impact. In this work, we report an electrochemical upcycling approach to electrocatalytic oxidation of PET hydrolysate using Cu-based nanowire catalysts. We demonstrate that the electrocatalyst can catalyze the ethylene glycol (EG) molecule derived from PET waste toward formate with high selectivity and exhibit a lower onset potential for EG oxidation than for water oxidation. Experimental and density functional theory calculation results reveal that the oxidation pathway of EG on CuO can selectively break the C-C bond to generate formic acid. This work sheds light on employing earth-abundant metal catalysts to convert PET plastic waste to produce valued chemicals and green hydrogen.