Elucidating the activity, mechanism and application of selective electrosynthesis of ammonia from nitrate on cobalt phosphide

作者：Shenghua Ye, Zhida Chen, Guikai Zhang, Wenda Chen, Chao Peng, Xiuyuan Yang, Lirong Zheng, Yongliang Li, Xiangzhong Ren, Huiqun Cao, Dongfeng Xue, Jieshan Qiu, Qianling Zhang, Jianhong Liu · 发表于：Energy & Environmental Science · 年份：2021 · DOI：10.1039/d1ee03097c · 被引用次数：394 · 研究领域：Ammonia Synthesis and Nitrogen Reduction、Advanced Photocatalysis Techniques、Catalytic Processes in Materials Science

Cobalt phosphide is an effective electrocatalyst for NO 3 − electroreduction into NH 3 . Phosphorus is crucial for stabilizing the active phase and optimizing energy barriers, and Co 4p orbitals directly participate in the nitrate reduction.