Complex Reorientation Dynamics of Sizable Glass-Formers with Polar Rotors Revealed by Dielectric Spectroscopy

作者：Marzena Rams‐Baron, Beibei Yao, Shinian Cheng, Mateusz Dulski, Marian Paluch · 发表于：The Journal of Physical Chemistry Letters · 年份：2021 · DOI：10.1021/acs.jpclett.1c03088 · 被引用次数：16 · 研究领域：Material Dynamics and Properties、Liquid Crystal Research Advancements、Geological and Geochemical Analysis

High Resolution Image Download MS PowerPoint Slide We present the results of dielectric measurements for three sizable glass-formers with identical nonpolar cores linked to various dipole-labeled rotors that shed new light on the picture of reorientation of anisotropic systems with significant moment of inertia revealed by broadband dielectric spectroscopy. The dynamics of sizable glass-formers formed by partially rigid molecular cores linked to small polar rotors in many respects differs from that of typical glass-formers. For instance, the extraordinarily large prefactors (τ 0 > 10 –12 s) in the Vogel–Fulcher–Tammann equation were found. The rich and highly diverse relaxation pattern was governed by the location of a dipole, its ability to rotate freely, and the degree of coupling to the motion of the entire sizable system.