High Performance Air Breathing Flexible Lithium–Air Battery

作者：Ahmad Jaradat, Chengji Zhang, Sachin Kumar Singh, Junaid Ahmed, Alireza Ahmadiparidari, Leily Majidi, Sina Rastegar, Zahra Hemmat, Shuxi Wang, Anh T. Ngo, Larry A. Curtiss, Matthew Daly, Arunkumar Subramanian, Amin Salehi‐Khojin · 发表于：Small · 年份：2021 · DOI：10.1002/smll.202102072 · 被引用次数：46 · 研究领域：Advanced Battery Materials and Technologies、Conducting polymers and applications、Advanced Sensor and Energy Harvesting Materials

Abstract Lithium–oxygen (Li–O 2 ) batteries possess the highest theoretical energy density (3500 Wh kg −1 ), which makes them attractive candidates for modern electronics and transportation applications. In this work, an inexpensive, flexible, and wearable Li–O 2 battery based on the bifunctional redox mediator of InBr 3 , MoS 2 cathode catalyst, and Fomblin‐based oxygen permeable membrane that enable long‐cycle‐life operation of the battery in pure oxygen, dry air, and ambient air is designed, fabricated, and tested. The battery operates in ambient air with an open system air‐breathing architecture and exhibits excellent cycling up to 240 at the high current density of 1 A g −1 with a relative humidity of 75%. The electrochemical performance of the battery including deep‐discharge capacity, and rate capability remains almost identical after 1000 cycle in a bending fatigue test. This finding opens a new direction for utilizing high performance Li–O 2 batteries for applications in the field of flexible and wearable electronics.