Al-Modified Ti-MOR as a robust catalyst for cyclohexanone ammoximation with enhanced anti-corrosion performance

作者：Rusi Peng, Zhipeng Wan, Huanzhi Lv, Yejun Guan, Hao Xu, Peng Wu · 发表于：Catalysis Science & Technology · 年份：2021 · DOI：10.1039/d1cy01396c · 被引用次数：18 · 研究领域：Catalysis and Hydrodesulfurization Studies、Catalytic Processes in Materials Science、Metal-Organic Frameworks: Synthesis and Applications

The skeleton desilication accompanied by Ti active sites leaching accounts for the dominant chemical deactivation reasons in the alkali liquid-phase ammoximation, which could be retarded by creating a protective Al-rich shell.