Boron containing metal–organic framework for highly selective photocatalytic production of H 2 O 2 by promoting two-electron O 2 reduction

作者：Yujie Li, Fahao Ma, Liren Zheng, Yuanyuan Liu, Zeyan Wang, Peng Wang, Zhaoke Zheng, Hefeng Cheng, Ying Dai, Baibiao Huang · 发表于：Materials Horizons · 年份：2021 · DOI：10.1039/d1mh00869b · 被引用次数：75 · 研究领域：Advanced Photocatalysis Techniques、Metal-Organic Frameworks: Synthesis and Applications、Perovskite Materials and Applications

The adsorption sites of boron in UiO-66-B lead to in a larger amount of O 2 adsorption; and the H + is adsorbed on the oxygen adjacent to boron, which is more conducive to the proton coupling reaction of ˙O 2 − to H 2 O 2 in the second step.