Synergistic Effect of Atomically Dispersed Ni–Zn Pair Sites for Enhanced CO 2 Electroreduction

作者：Youzhi Li, Bo Wei, Minghui Zhu, Jiacheng Chen, Qike Jiang, Bin Yang, Yang Hou, Lecheng Lei, Zhongjian Li, Ruifeng Zhang, Yingying Lü · 发表于：Advanced Materials · 年份：2021 · DOI：10.1002/adma.202102212 · 被引用次数：303 · 研究领域：CO2 Reduction Techniques and Catalysts、Electrocatalysts for Energy Conversion、Ionic liquids properties and applications

Abstract Dual‐atom catalysts have the potential to outperform the well‐established single‐atom catalysts for the electrochemical conversion of CO 2 . However, the lack of understanding regarding the mechanism of this enhanced catalytic process prevents the rational design of high‐performance catalysts. Herein, an obvious synergistic effect in atomically dispersed Ni–Zn bimetal sites is observed. In situ characterization combined with density functional theory (DFT) calculations reveals that heteronuclear coordination modifies the d‐states of the metal atom, narrowing the gap between the d‐band centre (ε d ) of the Ni (3d) orbitals and the Fermi energy level ( E F ) to strengthen the electronic interaction at the reaction interface, resulting in a lower free energy barrier (Δ G ) in the thermodynamic pathway and a reduced activation energy ( E a ) as well as fortified metal–C bonding in the kinetic pathway. Consequently, a CO faradaic efficiency of >90% is obtained across a broad potential window from − 0.5 to − 1.0 V (vs RHE), reaching a maximum of 99% at −0.8 V, superior to that of the Ni/Zn single‐metal sites.