Scandium and lanthanum hydride complexes stabilized by super-bulky penta-arylcyclopentadienyl ligands

作者：Yang Wang, Iker Del Rosal, Guorui Qin, Lanxiao Zhao, Laurent Maron, Xianghui Shi, Jianhua Cheng · 发表于：Chemical Communications · 年份：2021 · DOI：10.1039/d1cc01841h · 被引用次数：16 · 研究领域：Organometallic Complex Synthesis and Catalysis、Lanthanide and Transition Metal Complexes、Inorganic Chemistry and Materials

Bimetallic scandium complex [(Cp Ar5 )Sc(H)(μ-OC 4 H 9 )] 2 (Cp Ar5 = C 5 Ar 5 , Ar = 3,5- i Pr 2 -C 6 H 3 ) ( 2 ) with two terminal hydrido ligands, and lanthanum hydride complex [(Cp Ar5 )La(μ-H)] 2 ( 4 ) bearing the reduced Cp Ar5 ligand were obtained.