Assessment of ecotoxicity of spent fluid catalytic cracking (FCC) refinery catalysts on Raphidocelis subcapitata and predictive models for toxicity

作者：Yue-jie Wang, Chen Wang, Lingling Li, Yan Chen, Chunhong He, Zheng Lu · 发表于：Ecotoxicology and Environmental Safety · 年份：2021 · DOI：10.1016/j.ecoenv.2021.112466 · 被引用次数：13 · 研究领域：Radioactive element chemistry and processing、Analytical chemistry methods development、Environmental Toxicology and Ecotoxicology

The 17 spent fluid catalytic cracking refinery catalysts (SFCCCs) from different petroleum refineries were collected and the leachates of SFCCCs were prepared. The ecotoxicity of SFCCC leachates to Raphidocelis subcapitata was assayed. The results showed that the toxicity of the 17 SFCCCs differ greatly. Ji SFCCC was the most toxic to R. subcapitata with a 96 h EC50 value of 1.38%, while Ha SFCCC was the least toxic, with the EC50 value was >100%. The relationships between the toxicity of SFCCCs and the metal concentrations in leachates were analyzed. The concentration of Ni (p = 0.001), La (p = 0.001), Mn (p = 0.014), Ce (p = 0.017), Co (p = 0.018), and Ca (p = 0.031) in leachates showed significant correlation with EC50 values. The predictive model for the ecotoxicity of SFCCCs were established with the concentrations of Ni and La in leachates as: ln(EC50) = 0.817 + exp(1.356 – 1.736 × CNi - 0.262 × CLa) (R2 = 0.926). The main toxic ingredients of SFCCC to microalgae were identified for the first time in this work. The results and predictive model of this study are significance for toxicity determination and management of SFCCCs.