High-efficiency electrochemical nitrite reduction to ammonium using a Cu 3 P nanowire array under ambient conditions

作者：Jie Liang, Biao Deng, Qin Liu, Qin Liu, Guilai Wen, Qian Liu, Qian Liu, Tingshuai Li, Yonglan Luo, Abdulmohsen Ali Alshehri, Khalid A. Alzahrani, Dongwei Ma, Xuping Sun · 发表于：Green Chemistry · 年份：2021 · DOI：10.1039/d1gc01614h · 被引用次数：124 · 研究领域：Ammonia Synthesis and Nitrogen Reduction、Nanomaterials for catalytic reactions、Advanced Photocatalysis Techniques

Cu 3 P enables ambient electrosynthesis of ammonium via selective NO 2 − reduction, achieving a yield rate of 1626.6 ± 36.1 μg h −1 cm −2 and a Faradaic efficiency of 91.2 ± 2.5%. The catalytic mechanism is investigated by theoretical calculations.