Rhodium-Catalyzed Regioselective Hydroformylation of Alkynes to α,β-Unsaturated Aldehydes Using Formic Acid

作者：Chao Fan, Jing Hou, Yujia Chen, Kuiling Ding, Qi‐Lin Zhou · 发表于：Organic Letters · 年份：2021 · DOI：10.1021/acs.orglett.1c00234 · 被引用次数：33 · 研究领域：Carbon dioxide utilization in catalysis、Organoboron and organosilicon chemistry、Organometallic Complex Synthesis and Catalysis

A rhodium-catalyzed hydroformylation of alkynes with formic acid was developed. The method provides α,β-unsaturated aldehydes in high yield and E -selectivity without the need to handle toxic CO gas.