CaCl 2 molten salt hydrate-promoted conversion of carbohydrates to 5-hydroxymethylfurfural: an experimental and theoretical study

作者：Changqu Lin, Chaoqun Chai, Yuanzhang Li, Jiao Chen, Yanyu Lu, Hongli Wu, Lili Zhao, Fei Cao, Kequan Chen, Ping Wei, Pingkai Ouyang · 发表于：Green Chemistry · 年份：2021 · DOI：10.1039/d0gc04356g · 被引用次数：40 · 研究领域：Catalysis for Biomass Conversion、Biofuel production and bioconversion、Microbial Metabolites in Food Biotechnology

33.6% fructose and 52.1% HMF were achieved from glucose isomerization and dehydration in CaCl 2 salt hydrate. Interactions existing in β-glucopyranose-CaCl 2 and β- d -fructofuranose-Ca 2+ promoted the glucose isomerization and fructose dehydration.