Charge Transfer Parameters of NixMnyCo1−x−y Cathodes Evaluated by a Transmission Line Modeling Approach

作者：Janina Costard, Jochen Joos, Adrian Schmidt, Ellen Ivers‐Tiffée · 发表于：Energy Technology · 年份：2020 · DOI：10.1002/ente.202000866 · 被引用次数：21 · 研究领域：Advancements in Battery Materials、Advanced Battery Technologies Research、Advanced Battery Materials and Technologies

The performance of lithium‐ion batteries can be analyzed and improved by appropriate electrochemical models. A challenging yet crucial part is the parameterization of these models. Until now, the literature has incompletely investigated and cited the charge transfer process parameters describing the lithium transfer between the active material particles in the electrode and the liquid electrolyte. Herein, a novel approach is presented for obtaining these charge transfer parameters. The well‐established experimental methods of electrochemical impedance spectroscopy and focused ion beam tomography are applied. By introducing both experimental results into a transmission line model, a reliable determination of the charge transfer parameters j0, k, and rCT can be achieved. The new approach is validated by comparing the results of four cathodes, all containing the state‐of‐the‐art active material NixMnyCo1−x−y (NMC), but with different microstructures and/or stoichiometries.