Photocatalytic intermolecular anti -Markovnikov hydroamination of unactivated alkenes with N -hydroxyphthalimide

作者：Zhipeng Ye, Yuan‐Zhuo Hu, Peng‐Ju Xia, Hao‐Yue Xiang, Kai Chen, Hua Yang · 发表于：Organic Chemistry Frontiers · 年份：2020 · DOI：10.1039/d0qo01321h · 被引用次数：32 · 研究领域：Radical Photochemical Reactions、Catalytic C–H Functionalization Methods、Sulfur-Based Synthesis Techniques

A visible-light-induced/phosphite-promoted anti -Markovnikov hydroamination of alkenes with N -hydroxyphthalimide was successfully realized, which was initiated by a proton-coupled electron transfer to enable direct cleavage of its N–O bond.