Copper-zirconia interfaces in UiO-66 enable selective catalytic hydrogenation of CO2 to methanol

作者：Yifeng Zhu, Jian Wei Zheng, Jingyun Ye, Yanran Cui, Katherine Koh, Libor Kovařík, Donald M. Camaioni, John L. Fulton, Donald G. Truhlar, Matthew Neurock, Christopher J. Cramer, Oliver Y. Gutiérrez, Johannes A. Lercher · 发表于：Nature Communications · 年份：2020 · DOI：10.1038/s41467-020-19438-w · 被引用次数：211 · 研究领域：Catalysts for Methane Reforming、Metal-Organic Frameworks: Synthesis and Applications、CO2 Reduction Techniques and Catalysts

Abstract Molecular interactions with both oxides and metals are essential for heterogenous catalysis, leading to remarkable synergistic impacts on activity and selectivity. Here, we show that the direct link between the two phases (and not merely being together) is required to selectively hydrogenate CO 2 to methanol on catalysts containing Cu and ZrO 2 . Materials consisting of isolated Cu particles or atomically dispersed Cu–O–Zr sites only catalyze the reverse water-gas shift reaction. In contrast, a metal organic framework structure (UiO-66) with Cu nanoparticles occupying missing-linker defects maximizes the fraction of metallic Cu interfaced to ZrO 2 nodes leading to a material with high adsorption capacity for CO 2 and high activity and selectivity for low-temperature methanol synthesis.