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Coreduction methodology for immiscible alloys of CuRu solid-solution nanoparticles with high thermal stability and versatile exhaust purification ability

作者:Bo Huang, Hirokazu Kobayashi, Tomokazu Yamamoto, Syo Matsumura, Yoshihide Nishida, Katsutoshi Sato, Katsutoshi Nagaoka, Masaaki Haneda, Shogo Kawaguchi, Yoshiki Kubota, Hiroshi Kitagawa · 发表于:Chemical Science · 年份:2020 · DOI:10.1039/d0sc03373a · 被引用次数:29 · 研究领域:nanoparticles nucleation surface interactions、Copper-based nanomaterials and applications、Chalcogenide Semiconductor Thin Films

infrared measurements, stronger NO adsorption and higher intrinsic reactivity of the Ru site on the CuRu surface than that of a pure Ru surface were found, affected by atomic-level Cu substitution. Furthermore, CuRu solid solution was a versatile catalyst for purification of all exhaust gases at a stoichiometric oxygen concentration.