Exploring the fate of heavy metals from mining and smelting activities in soil-crop system in Baiyin, NW China

作者：Bihong He, Wei Wang, Rongyue Geng, Zhe Ding, Dongxia Luo, Junli Qiu, Guodong Zheng, Qiaohui Fan · 发表于：Ecotoxicology and Environmental Safety · 年份：2020 · DOI：10.1016/j.ecoenv.2020.111234 · 被引用次数：73 · 研究领域：Heavy metals in environment、Heavy Metal Exposure and Toxicity、Mercury impact and mitigation studies

The activity and fate of heavy metals (HMs) from mining and smelting activities in farmland soil is of great significance to effectively prevent the excessive enrichment of HMs in crops. This study focuses on Baiyin area, a typical mining city in northwest China. In this example, the sources, speciation, and fate of HMs in the farmland soil, and the migration and enrichment characteristics of HMs in the different parts of crops planted in different areas were studied in detail combining the chemical sequential extraction and Pb isotope approaches. Results showed that the mean anthropogenic contributions of HMs in farmland soils were approximately 85%, 88%, 76%, and 41% for the ore district (OD), Xidagou sewage irrigation area (XSIA), Dongdagou sewage irrigation area, and the Yellow River irrigation area, respectively, and the risk that HMs were excessively accumulated in crops in OD and XSIA was high. Compared with soil residual fractions, the isotope ratios 206Pb/207Pb in non-residual fractions (1.1304–1.1669) were closer to the values of local ores, suggesting that anthropogenic HMs from mining and smelting activities were mainly enriched in the non-residual fractions. The isotope ratios 206Pb/207Pb in crops (1.1398–1.1686) further confirmed that those anthropogenic HMs were more easily absorbed and concentrated by crops. HMs contents in leaves from OD and XSIA were generally higher than that in roots, suggesting that atmospheric deposition in OD and XSIA had a greater impa...