All-thiolate-stabilized Ag42 nanocluster with a tetrahedral kernel and its transformation to an Ag61 nanocluster with a bi-tetrahedral kernel

作者：Tao Chen, Sha Yang, Yongbo Song, Jinsong Chai, Qinzhen Li, Xiangyu Ma, Guang Li, Haizhu Yu, Manzhou Zhu · 发表于：Chemical Communications · 年份：2020 · DOI：10.1039/d0cc02537b · 被引用次数：22 · 研究领域：Nanocluster Synthesis and Applications、Gold and Silver Nanoparticles Synthesis and Applications

Two new silver nanoclusters, formulated as Ag42 (SBu t ) 24 and Ag61 (SC 6 H 11 ) 40 Cl were prepared by a NaSbF 6 -mediated two-phase ligand exchange method. A size conversion from Ag42 to Ag61 were achieved via cyclohexanethiol etching.