Solid-state nanocrystalline dye-sensitized solar cell using 2-mercapto benzimidazole doped poly (ethylene oxide) as a new polymer electrolyte

作者：Muthuraaman Bhagavathi Achari, S. Ganesan, Srinivasan Latha, P. Maruthamuthu, S. Austin Suthanthiraraj, Jeffrey Bell, Paul Moonie · 年份：2008 · 研究领域：TiO2 Photocatalysis and Solar Cells、Conducting polymers and applications、Analytical Chemistry and Sensors

New composite doped poly (ethylene oxide) polymer electrolyte was developed using 2-mercapto benzimidazole as plasticizer and iodide/triiodide as redox couple. The fabrication of the cell involves Poly(ethylene oxide)/ 2-mercapto benzimidazole / iodide/triiodide as polymer electrolyte in dye-sensitized solar cell fabricated with N3 dye and TiO2 nanoparticles as the photoanode and Platinum coated FTO (fluorine doped SnO2) as counter electrode. The current-volatage characteristics under simulated sunlight AM1.5 shows a short circuit current Isc of 8.7mA and open circuit photovoltage 508 mV. The conductivity measurements for the new polymer electrolyte and the photoelectrochemical measurments were carried out systematically. In 2-mercapto benzimidazole the electron rich sulphur and nitrogen atoms, act as pi-electron donors that form good interaction with iodine which plays a vital role in the performance of the fabricated dye-sensitized solar cells. The resonance effect increases the stability of the cell to a considerable extent. These results suggest that the new composite polymer electrolyte performs as a promising new doped polymer-electrolyte.