Column adsorption study for the removal of chromium and manganese ions from electroplating wastewater using cashew nutshell adsorbent

作者：Muibat Diekola Yahya, Abdulmajeed Aliyu, Kehinde Shola Obayomi, Adeola Grace Olugbenga, U. B. Abdullahi · 发表于：Cogent Engineering · 年份：2020 · DOI：10.1080/23311916.2020.1748470 · 被引用次数：83 · 研究领域：Adsorption and biosorption for pollutant removal、Nanomaterials for catalytic reactions、Extraction and Separation Processes

The aim of this study is to evaluate the potential of cashew nutshell activated with H2SO4 as adsorbent for the removal of Cr and Mn (II) ions from wastewater. In this study, cashew nutshell (CNS) adsorbent was prepared using shells of cashew nut (Anacardium occidentale) by chemical activation. Cashew nutshells were crushed for size reduction and the resulting crushed shells were immersed in 1.0 mol L−1 H2SO4 at a rate of 1:10 (m/v) with a constant stirring at 60°C for 4 h. Proximate analysis was carried out according to standard analytical methods and determination of pH, bulk density, and iodine number was conducted. The morphology and functional groups present were investigated by Scanning Electron Microscopy (SEM) and Fourier Transform Infrared (FT-IR) spectroscopy. The surface area, pore volume, and pore size distribution were also characterized by N2 adsorption at 77 K using BET. Continuous adsorption study in a fixed-bed column was carried out by using CNS as an adsorbent for the removal of chromium and manganese ions from electroplating wastewater. The effect of flow rate, influent concentration, and bed depth were investigated on the adsorption characteristics of the CNS adsorbent. Three dynamic model Clark, Yoon-Nelson, and Adams-Bohart were applied using the experimental data to predict the breakthrough curves using linear regression to determine the characteristic parameters of the column that are useful for process design. Significant values in the moisture, ash ...