Highly dispersed Co-Mo sulfide nanoparticles on reduced graphene oxide for lithium and sodium ion storage

作者：Yuqing Liao, Chun Wu, Yaotang Zhong, Min Chen, Luyang Cai, Huirong Wang, Xiang Liu, Guozhong Cao, Weishan Li · 发表于：Nano Research · 年份：2020 · DOI：10.1007/s12274-019-2594-2 · 被引用次数：37 · 研究领域：Advancements in Battery Materials、Advanced Battery Materials and Technologies、Supercapacitor Materials and Fabrication

A novel hybrid, highly dispersed spinel Co-Mo sulfide nanoparticles on reduced graphene oxide (Co 3 S 4 /CoMo 2 S 4 @rGO), is reported as anode for lithium and sodium ion storage. The hybrid is synthesized by one-step hydrothermal method but exhibits excellent lithium and sodium storage performances. The as-synthesized Co 3 S 4 /CoMo 2 S 4 @rGO presents reversible capacity of 595.4 mA·h·g −1 and 408.8 mA·h·g −1 after 100 cycles at a current density of 0.2 A·g −1 for lithium and sodium ion storages, respectively. Such superior performances are attributed to the unique composition and structure of Co 3 S 4 /CoMo 2 S 4 @rGO. The rGO provides a good electronically conductive network and ensures the formation of spinel Co 3 S 4 /CoMo 2 S 4 nanoparticles, the Co 3 S 4 /CoMo 2 S 4 nanoparticles provide large reaction surface for lithium and sodium intercalation/deintercalation, and the spinel structure allows fast lithium and sodium ion diffusion in three dimensions.