Mixed Spacer Cation Stabilization of Blue‐Emitting n = 2 Ruddlesden–Popper Organic–Inorganic Halide Perovskite Films

作者：Tik Lun Leung, Ho Won Tam, Fangzhou Liu, Jingyang Lin, Alan Man Ching Ng, Wai Kin Chan, Wei Chen, Zhubing He, Ivor Lončarić, Luca Grisanti, Chao Ma, Kam Sing Wong, Ying Suet Lau, Furong Zhu, Željko Skoko, Jasminka Popović, Aleksandra B. Djurišić · 发表于：Advanced Optical Materials · 年份：2019 · DOI：10.1002/adom.201901679 · 被引用次数：52 · 研究领域：Perovskite Materials and Applications、Organic Light-Emitting Diodes Research、Organic Electronics and Photovoltaics

Abstract Ruddlesden–Popper halide perovskite (RPP) materials are of significant interest for light‐emitting devices since their emission wavelength can be controlled by tuning the number of layers n , resulting in improved spectral stability compared to mixed halide devices. However, RPP films typically contain phases with different n , and the low n phases tend to be unstable upon exposure to humidity, irradiation, and/or elevated temperature which hinders the achievement of pure blue emission from n = 2 films. In this work, two spacer cations are used to form an RPP film with mixed cation bilayer and high n = 2 phase purity, improved stability, and brighter light emission compared to a single spacer cation RPP. The stabilization of n = 2 phase is attributed to favorable formation energy, reduced strain, and reduced electron–phonon coupling compared to the RPP films with only one type of spacer cation. Using this approach, pure blue light‐emitting diodes (LEDs) with Commission Internationale de l'éclairage (CIE) coordinates of (0.156, 0.088) and excellent spectral stability are achieved.