A Recyclable bi‐functional Luminescent Zinc (II) metal–organic framework as highly selective and sensitive sensing probe for nitroaromatic explosives and Fe 3+ ions

作者：Enjun Gao, Dongsheng Liu, Jialing Xing, Yunhui Feng, Junqi Su, Jiaxing Liu, Hongwei Zhao, Ning Wang, Zhili Jia, Xiaoyin Zhang, Vladimir P. Fedin, Mingchang Zhu · 发表于：Applied Organometallic Chemistry · 年份：2019 · DOI：10.1002/aoc.5109 · 被引用次数：12 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Molecular Sensors and Ion Detection、Luminescence and Fluorescent Materials

By introducing carboxyl tag to the aromatic ligands system and borrowing the organic template open framework idea, a stable fluorescent Zn metal–organic framework was successfully prepared through a rigid ligand H 6 L (3,5‐bis‐(3‐carboxyphenoxy)benzoic acid) under hydrothermal conditions. The selectivity and sensitivity of the Zn‐MOF to metal ions and nitro‐aromatic compounds (NACs) were investigated by fluorescence quenching. And the Zn‐MOF showed a high sensibility of nitro‐aromatic compounds (NACs) and Fe 3+ ions, especially for 4‐(4‐nitropheny lazo) resorcinol (NPLR). More importantly, the detection limit of the Zn‐MOF for detecting NPLR solution was found to be 1.71 ppb. Moreover, this sensor is remarkable recyclable and is promisingly applied for rapid, on‐site and sensing of explosive residuals.