Boosted Interfacial Polarization from Multishell TiO 2 @Fe 3 O 4 @PPy Heterojunction for Enhanced Microwave Absorption

作者：Jingjun Ding, Lei Wang, Yunhao Zhao, Linshen Xing, Xue‐Feng Yu, Guanyu Chen, Jie Zhang, Renchao Che · 发表于：Small · 年份：2019 · DOI：10.1002/smll.201902885 · 被引用次数：414 · 研究领域：Electromagnetic wave absorption materials、Advanced Antenna and Metasurface Technologies、Magnetic Properties and Synthesis of Ferrites

Abstract Core@shell structures have been attracting extensive attention to boost microwave absorption (MA) performance due to the unique interfacial polarization. However, it still remains a challenge to synthesize sophisticated 1D semiconductor‐based materials with excellent MA competence. Herein, a hierarchical cable‐like TiO 2 @Fe 3 O 4 @PPy is fabricated by a sequential process of solvothermal treatment and polymerization. The complex permittivity of ternary composites can be optimized by tunable PPy coating thickness to improve the loss ability. The maximum reflection loss can reach −61.8 dB with a thickness of 3.2 mm while the efficient absorption bandwidth can achieve over 6.0 GHz, which involves the X and Ku band at only a 2.2 mm thickness. Importantly, the heterojunction contacts constructed by PPy–Fe 3 O 4 and Fe 3 O 4 –TiO 2 contribute to the enhanced polarization loss. Besides, the configuration of magnetic Fe 3 O 4 sandwiched between dielectric TiO 2 and PPy facilitates the magnetic stray field to radiate into the TiO 2 core and out of the PPy shell, which significantly promotes magnetic–dielectric synergy. Electron holography validates the distinct charge distribution and magnetic coupling. The new findings might shed light on novel structures for functional core@shell composites and the design of semiconductor‐based materials for microwave absorption.