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Crystal Structure and Thermal Properties of Copper Complex with N-(2-Pyridyl)-2-Naphthoic Amide

作者:Q. Huang, Yanqing Zhao, Xu Wei · 发表于:Russian Journal of Inorganic Chemistry · 年份:2019 · DOI:10.1134/s0036023619050085 · 被引用次数:2 · 研究领域:Chemical Thermodynamics and Molecular Structure、Crystal structures of chemical compounds、Thermal and Kinetic Analysis

Complex Cu(SCN)2(CH3OH)2(NPNAA)2 (I) has been prepared by the reaction between Cu(OAc)2 with KSCN and the organic ligand N-(4-pyridyl)-2-naphthoic amide (NpNAA) by solvent evaporation method and structurally characterized by single-crystal X-ray diffraction. Complex I crystallizes in a triclinic system with space group $$P\overline 1 $$ . The three-dimensional solid-state structure of complex I is constructed by the strong π⋯π stacking effects between the bulky aromatic rings. The thermal properties of complex I have been investigated in air.