Measurement of Dioxin Emissions from a Small-Scale Waste Incinerator in the Absence of Air Pollution Controls

作者：Gang Zhang, Xiangxuan Huang, Wenbo Liao, Shimin Kang, Mingzhong Ren, Jing Hai · 发表于：International Journal of Environmental Research and Public Health · 年份：2019 · DOI：10.3390/ijerph16071267 · 被引用次数：35 · 研究领域：Toxic Organic Pollutants Impact、Recycling and Waste Management Techniques、Municipal Solid Waste Management

-dioxin and dibenzofuran (PCDD/Fs) emissions from basic small-scale waste incinerators (SWI) may cause health risks in nearby people and are thus subject to stringent regulations. The aim of this study was to evaluate PCDD/F emission and reduction of a basic SWI in the absence of air pollution controls (APCs). The results indicated that the stack gas and fly ash presented average PCDD/F levels and emission factors of 3.6 ng international toxic equivalent (I-TEQ)/Nm³ and 189.31µg I-TEQ/t and 6.89 ng I-TEQ/g and 137.85µg I-TEQ/t, respectively, much higher than those from large municipal solid waste incinerators (MSWI). PCDD/Fs congener fingerprints indicated that de novo synthesis played a dominant role in the low-temperature post-combustion zone and increased the presence of high-chlorine substituted congeners. On the basis of the emission factor 327.24 µg I-TEQ/t-waste, approximately 3000 g I-TEQ dioxins might be generated in total through basic SWIs and open burning. After refitting an SWI by adding activated carbon injection with a bag filter (ACI+BG), the PCDD/F emissions decreased to mean values of 0.042 ng I-TEQ/Nm³, far below the standard of 0.1 ng I-TEQ/Nm³, and the removal efficiency reached 99.13% in terms of I-TEQ. Therefore, it is entirely feasible to considerably reduce PCDD/F emissions by refitting basic SWI, which is positive for the future development of rural solid waste (RSW (RSW) disposal by SWI.