Fabrication and simulation analysis of flexible polymethylsilsesquioxane (PMSQ) aerogels by using dimethyl sulfoxide (DMSO) as solvent

作者：Fei He, Liang Zhou, Minhan Fang, Chao Sui, Wenjie Li, Lijuan Yang, Mingwei Li, Xiaodong He · 发表于：Materials & Design · 年份：2019 · DOI：10.1016/j.matdes.2019.107777 · 被引用次数：36 · 研究领域：Aerogels and thermal insulation、Surface Modification and Superhydrophobicity、Silicone and Siloxane Chemistry

The flexible bulk polymethylsilsesquioxane (PMSQ) aerogels were synthesized using DMSO as solvent via the sol-gel process and supercritical drying. The porous microstructures and the bonding linkage were investigated by means of Fourier transform infrared (FT-IR) spectra, nitrogen adsorption-desorption method and scanning electron microscopy (SEM). The effects of dimethyl sulfoxide (DMSO) and ammonium hydroxide (AH) in sol-gel process were discussed. The results show that the micro-morphology of PMSQ aerogels is an expression of freezing siloxane system by adjusting the relative ratio of DMSO and AH. The PMSQ aerogels are provided with high specific surface area, low density, favorable flexibility and low thermal conductivity. The multi-scale simulative analysis reveals that DMSO as solvent tends to uniformly disperse M-monomer due to similar solubility parameter (SP) and repulsion parameter (RP). SP and RP can be regarded as important parameters of solvent selection to explain and predict gel compatibility and uniformity.