Mg–Mg-bonded compounds with N , N ′-dipp-substituted phenanthrene-diamido and o -phenylene-diamino ligands

作者：Meimei Ma, Huanhuan Wang, Juju Wang, Lingyi Shen, Yanxia Zhao, Wenhua Xu, Biao Wu, Xiao‐Juan Yang · 发表于：Dalton Transactions · 年份：2019 · DOI：10.1039/c9dt00028c · 被引用次数：26 · 研究领域：Coordination Chemistry and Organometallics、Catalytic Cross-Coupling Reactions、N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Two Mg-Mg-bonded compounds were synthesized by using the ligands N,N'-bis(dipp)-phenanthrene-9,10-diimine (L2) and N,N'-bis(dipp)-o-phenylenediamine (H2L3; dipp = 2,6-diisopropylphenyl). These new Mg(i) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.