Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis

作者：Jianhui Chen, Jun Guo, Zhan Ling Lu · 发表于：Chinese Journal of Chemistry · 年份：2018 · DOI：10.1002/cjoc.201800314 · 被引用次数：527 · 研究领域：Catalytic C–H Functionalization Methods、Catalytic Cross-Coupling Reactions、Asymmetric Hydrogenation and Catalysis

Abstract Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐ or alkenyl‐metal reagents, which have a wide range of applications in organic transformations. In recent years, the first row transition metals (such as copper, nickel, cobalt, iron, etc .) have emerged high activity and selectivity in this area with the aid of a variety of ligands. This review covers the recent advances in the hydrometallation of minimally functionalized unsaturated C—C bonds (including alkenes, alkynes, dienes, allenes, enynes, etc .), as well as transformations involving catalytic hydrometallation process via the first row transition metal catalysis.