Synthesis of Thiophosphates by Coupling of Phosphates with Bunte Salts under Mild Conditions

作者：Sen Lin, Zhaohua Yan, Cong Min, Rongxing Zhang, Qian Liu · 发表于：Synlett · 年份：2018 · DOI：10.1055/s-0037-1609556 · 被引用次数：3 · 研究领域：Sulfur-Based Synthesis Techniques、Organophosphorus compounds synthesis、Synthesis and Reactivity of Sulfur-Containing Compounds

A simple, green, and efficient method has been developed for the preparation of thiophosphates with sodium S-benzyl thiosulfates. The method uses an NaBr-catalyzed coupling reaction of Bunte salts with phosphonates in the presence of an acid and hydrogen peroxide (30%), and the desired products were obtained in good yields.