A photocatalytic iminyl radical-mediated C–C bond cleavage/addition/cyclization cascade for the synthesis of 1,2,3,4-tetrahydrophenanthrenes

作者：Peng‐Zi Wang, Xiaoye Yu, Chan-Yun Li, Bin‐Qing He, Jia‐Rong Chen, Wen‐Jing Xiao · 发表于：Chemical Communications · 年份：2018 · DOI：10.1039/c8cc06145a · 被引用次数：80 · 研究领域：Radical Photochemical Reactions、Catalytic C–H Functionalization Methods、Sulfur-Based Synthesis Techniques

On the basis of the strategy of iminyl radical-mediated C-C bond cleavage, a visible light photocatalytic radical addition/cyclization cascade is described, providing an efficient and regioselective access to cyanoalkylated 1,2,3,4-tetrahydrophenanthrenes.