Plasma processes to detect fluorine with ICPMS/MS as [M–F] + : an argument for building a negative mode ICPMS/MS

作者：Nor Laili‐Azua Jamari, Arne Behrens, Andrea Raab, Eva M. Krupp, Jörg Feldmann · 发表于：Journal of Analytical Atomic Spectrometry · 年份：2018 · DOI：10.1039/c8ja00050f · 被引用次数：43 · 研究领域：Analytical chemistry methods development、Mass Spectrometry Techniques and Applications、Molecular Sensors and Ion Detection

The paper describes that the 2 nd ionisation potential and the difference in bond energy of a metal to fluorine bond and of a metal to oxygen bond are the most important parameters to form a metal fluoride ion for the detection of fluorine in ICPMS/MS.