Prussian Blue Cathode Materials for Sodium‐Ion Batteries and Other Ion Batteries

作者：Jiangfeng Qian, Chen Wu, Yuliang Cao, Zi‐Feng Ma, Yunhui Huang, Xinping Ai, Hanxi Yang · 发表于：Advanced Energy Materials · 年份：2018 · DOI：10.1002/aenm.201702619 · 被引用次数：875 · 研究领域：Advancements in Battery Materials、Advanced Battery Materials and Technologies、Supercapacitor Materials and Fabrication

Abstract Sodium‐ion batteries (SIBs) are considered to be a low‐cost complement or competitor to Li‐ion batteries for large‐scale electric energy storage applications; however, their development has been less successful due to the lack of suitable host materials to enable reversible Na+ insertion reactions. Prussian blue analogs (PBAs) appear to be attractive candidates for SIB cathodes because of their open channel structure, compositional and electrochemical tunability. In this paper, the authors present a comprehensive review on the recent advances in the development of PBA frameworks as SIB cathodes with particular attention to the structure‐performance correlation of the PBA materials, and discuss the possible strategies to address the problems present in the SIB applications of PBAs. Also, the development of the PBA frameworks for the insertion cathodes of other monovalent and multivalent ions is briefly introduced, with the aim of providing a new insight into the design and development of new host materials for the next‐generation advanced batteries.