Direct evidence of charge separation in a metal–organic framework: efficient and selective photocatalytic oxidative coupling of amines via charge and energy transfer

作者：Caiyun Xu, Hang Liu, Dandan Li, Ji‐Hu Su, Hai‐Long Jiang · 发表于：Chemical Science · 年份：2018 · DOI：10.1039/c7sc05296k · 被引用次数：319 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Advanced Photocatalysis Techniques、Covalent Organic Framework Applications

For the first time, the photoexcited charge separation in a metal–organic framework has been evidenced with clear ESR signals, based on efficient and selective photocatalytic oxidative coupling of amines.