Organoselenium-Catalyzed Oxidative C═C Bond Cleavage: A Relatively Green Oxidation of Alkenes into Carbonyl Compounds with Hydrogen Peroxide

作者：Tingting Wang, Xiaobi Jing, Chao Chen, Lei Yu · 发表于：The Journal of Organic Chemistry · 年份：2017 · DOI：10.1021/acs.joc.7b01245 · 被引用次数：95 · 研究领域：Organoselenium and organotellurium chemistry、Vanadium and Halogenation Chemistry、Sulfur-Based Synthesis Techniques

A relatively green oxidative C═C bond cleavage of alkenes was achieved by organoselenium-catalyzed alkene oxidation reaction in ethanol with hydrogen peroxide, affording carbonyl compounds under relatively mild conditions. It is a new reaction style for the organoselenium-catalyzed oxidation of alkenes and largely contributes to the growing field of organoselenium catalysis.