Synthesis of Isoquinolines from Benzimidates and Alkynes via Cobalt(III)-Catalyzed C–H Functionalization/Cyclization

作者：Shasha Gong, Wanlin Xi, Zhenhua Ding, Haiying Sun · 发表于：The Journal of Organic Chemistry · 年份：2017 · DOI：10.1021/acs.joc.7b01052 · 被引用次数：33 · 研究领域：Catalytic C–H Functionalization Methods、Synthesis and Catalytic Reactions、Sulfur-Based Synthesis Techniques

C-H alkenylation/annulation of benzimidates with alkynes has been realized by using a Cp*Co(III) catalyst under air. A series of substituted isoquinolines were obtained with moderate to good yields under mild reaction conditions.