Cyclometalated Ir( iii ) complexes based on 2-(2,4-difluorophenyl)-pyridine and 2,2′-(2-phenyl-1H-imidazole-4,5-diyl)dipyridine: acid/base-induced structural transformation and luminescence switching, and photocatalytic activity for hydrogen evolution
作者:Tai-Bao Gao, Qianwenhao Fan, Zhen‐Tao Yu, Deng‐Ke Cao · 发表于:Dalton Transactions · 年份:2017 · DOI:10.1039/c7dt01337j · 被引用次数:14 · 研究领域:Nanocluster Synthesis and Applications、Radical Photochemical Reactions、Catalytic C–H Functionalization Methods
1 ·PF 6 and 2 show luminescence switching behaviors, and serve as photosensitizers for H 2 evolution.