Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex

作者：Jingjing Guo, Anhua Hu, Yilin Chen, Jianfeng Sun, Haoming Tang, Zhiwei Zuo · 发表于：Angewandte Chemie International Edition · 年份：2016 · DOI：10.1002/anie.201609035 · 被引用次数：345 · 研究领域：Radical Photochemical Reactions、Catalytic C–H Functionalization Methods、Synthesis and Catalytic Reactions

A general strategy for the cleavage and amination of C-C bonds of cycloalkanols has been achieved through visible-light-induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C-C bond cleavage and functionalization of unstrained secondary cycloalkanols.