In Situ Observation of Hydrogen‐Induced Surface Faceting for Palladium–Copper Nanocrystals at Atmospheric Pressure

作者：Ying Jiang, Hengbo Li, Zhemin Wu, Wenying Ye, Hui Zhang, Yong Wang, Chenghua Sun, Ze Zhang · 发表于：Angewandte Chemie International Edition · 年份：2016 · DOI：10.1002/anie.201605956 · 被引用次数：109 · 研究领域：Copper-based nanomaterials and applications、nanoparticles nucleation surface interactions、Gold and Silver Nanoparticles Synthesis and Applications

Nanocrystal (NC) morphology, which decides the number of active sites and catalytic efficiency, is strongly determined by the gases involved in synthesis, treatment, and reaction. Myriad investigations have been performed to understand the morphological response to the involved gases. However, most prior work is limited to low pressures, which is far beyond realistic conditions. A dynamic morphological evolution of palladium-copper (PdCu) NC within a nanoreactor is reported, with atmospheric pressure hydrogen at the atomic scale. In situ transmission electron microscopy (TEM) videos reveal that spherical PdCu particles transform into truncated cubes at high hydrogen pressure. First principles calculations demonstrate that the surface energies decline with hydrogen pressure, with a new order of γH-001 <γH-110 <γH-111 at 1 bar. A comprehensive Wulff construction based on the corrected surface energies is perfectly consistent with the experiments. The work provides a microscopic insight into NC behaviors at realistic gas pressure and is promising for the shaping of nanocatalysts by gas-assisted treatments.