Vibrationally resolved electron-nuclear energy sharing in above-threshold multiphoton dissociation of CO

作者：Xufei Sun, Min Li, Yun Shao, Mingming Liu, Xiguo Xie, Yongkai Deng, Chengyin Wu, Qihuang Gong, Yunquan Liu · 发表于：Physical Review A · 年份：2016 · DOI：10.1103/physreva.94.013425 · 被引用次数：22 · 研究领域：Laser-Matter Interactions and Applications、Advanced Chemical Physics Studies、Mass Spectrometry Techniques and Applications

We study the photon energy sharing between the photoelectron and the nuclei in the process of above-threshold multiphoton dissociative ionization of CO molecules by measuring the joint energy spectra. The experimental observation shows that the electron-nuclear energy sharing strongly depends on the vibrational state. The experimental observation shows that both the energy deposited to the nuclei of $\mathrm{C}{\mathrm{O}}^{+}$ and the emitted photoelectron decrease with increasing the vibrational level. Through studying the vibrationally resolved nuclear kinetic energy release and photoelectron energy spectra at different laser intensities, for each vibrational level of $\mathrm{C}{\mathrm{O}}^{+}$, the nuclei always tend to take the same amount of energy in every vibrational level regardless of the laser intensity, while the energy deposited to the photoelectron varies with respect to the laser intensity because of the ponderomotive shifted energy and the distinct dissociative ionization mechanisms.