Boosting High‐Rate Lithium Storage of V 2 O 5 Nanowires by Self‐Assembly on N‐Doped Graphene Nanosheets

作者：Xiaotian Gao, Xiaodong Zhu, Shiru Le, Du‐Juan Yan, Cai‐Yu Qu, Yujie Feng, Kening Sun, Yitao Liu · 发表于：ChemElectroChem · 年份：2016 · DOI：10.1002/celc.201600305 · 被引用次数：35 · 研究领域：Advancements in Battery Materials、Supercapacitor Materials and Fabrication、Transition Metal Oxide Nanomaterials

Abstract V 2 O 5 is a promising cathode material for lithium‐ion batteries owing to its extremely high theoretical capacity (440 mA h g −1 when storing 3 Li + ions and 294 mA h g −1 when storing 2 Li + ). However, drawbacks such as a strong inclination to aggregate and the low conductivity inherent to nanostructured V 2 O 5 drastically deteriorate its cycle and rate performances. Hence, hybridizing it with a conductive matrix (e.g. graphene) for improved electrochemical performance is an interesting concept. It is well established that heteroatom functionalization (e.g. N doping) can tailor the chemical properties of graphene by influencing the neighboring carbon atoms to enhance conductivity and electrochemical activity. Herein, a high‐rate cathode material is fabricated by self‐assembly of V 2 O 5 nanowires on N‐doped graphene nanosheets, followed by heat treatment to optimize the electrochemical performance. The synergistic effects of the resulting V 2 O 5 /N‐doped graphene nanohybrids are demonstrated by their excellent rate capability: they deliver very high capacities of 273, 242, 206, 181, and 161 mA h g −1 at current densities of 100, 200, 500, 1000, and 2000 mA g −1 .