A Palladium‐Catalyzed Domino Approach to 2,3‐Disubstituted Benzofurans via an Intermolecular Carbopalladation/C(sp3)−H Functionalization/Isomerization Sequence

作者：Siva Senthil Kumar Boominathan, Ruei‐Jhih Hou, Wan‐Ping Hu, Po‐Jui Huang, Jeh‐Jeng Wang · 发表于：Advanced Synthesis & Catalysis · 年份：2016 · DOI：10.1002/adsc.201600356 · 被引用次数：18 · 研究领域：Catalytic C–H Functionalization Methods、Catalytic Cross-Coupling Reactions、Cyclopropane Reaction Mechanisms

Abstract A palladium‐catalyzed domino strategy has been developed for the synthesis of 2,3‐disubstituted benzofuran derivatives. This cascade reaction sequence involves intermolecular carbopalladation and C( sp 3 )−H functionalization followed by isomerization. magnified image