Stereumins H−J, Stereumane-Type Sesquiterpenes from the Fungus Stereum sp.

作者：Guo-Hong Li, Fangfang Liu, Lan Shen, Hua‐Jie Zhu, Ke‐Qin Zhang · 发表于：Journal of Natural Products · 年份：2011 · DOI：10.1021/np100813f · 被引用次数：39 · 研究领域：Fungal Biology and Applications、Microbial Natural Products and Biosynthesis、Chemical synthesis and alkaloids

Stereumins H (1), I (2), and J (3), three sesquiterpenes possessing a novel stereumane-type backbone, were isolated from an extract of culture broth of the Basidiomycete Stereum sp. CCTCC AF 207024. The complete structural assignments including the absolute configurations are reported by using X-ray studies and density functional theory at the B3LYP/aug-cc-pVDZ//B3LYP/6-31G(d) level.